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Academic Journal

Unprotected and interconnected Ru0 nano-chain networks: advantages of unprotected surfaces in catalysis and electrocatalysis† †Electronic supplementary information (ESI) available: Information on reagents, instrumentation and analytical techniques employed are elaborated. Detailed calculation of conversion, selectivity, yield, TON, TOF and the rate constants for catalytic nitroarenes hydrogenation is given. TOF calculation for the electrocatalytic water splitting is explained. Calibration curves for finding the real concentrations of the nitro compounds as Fig. S1A–F and the corresponding concentration are provided as Table S1. Details on the construction of calibration curves are given. XRD and EDS spectra are given as Fig. S2 and S3A–C. The detailed concentration of nitroarenes taken for catalytic study and other reaction parameters are tabulated as Table S2. The comparative interpretation for the catalytic activity of unprotected Ru0 nano-chain networks with the Ru catalysts in other forms and noble metal catalysts are provided as Tables S3 and S4. The LDPS particle size distribution is provided as Fig. S4A–C. The time dependent UV-Vis spectra and the corresponding first order kinetic plots for all nitroarenes except 4-NS are provided as Fig. S5A–M and N–Z. UV-Vis spectra, TEM micrographs and electron diffraction patterns of Ru-CTAB, Ru-SDS and Ru-TX-100 are provided as Fig. S6A–I. The time-dependent UV-Vis spectra for the hydrogenation of 4-NS by Ru-CTAB, Ru-SDS and Ru-TX-100 and their corresponding ln(conc.) vs. time plots are given as Fig. S7A–F. CV of Ru-30, Ru-45 and Ru-60 are given together as Fig. S8. Post-cycle CV for Ru-60 after 10 h of chronoamperometric analysis is given as Fig. S9. CV of Ru-60 modified GC with the potential window of –1 to 1 V for identifying the non-faradaic region is given as Fig. S10. See DOI:10.1039/c5sc04714e

Subjects: Chemistry

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